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Creators/Authors contains: "Qiao, Quinn"

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  1. Lithium metal is considered as an ideal anode for high-energy density storage systems with dendrites being a major issue for lifetime and safety. A gadolinium additive is found to be suppressing dendrite growth resulting higher performance retention. 
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  2. Abstract Metal halide perovskites show promise for next-generation light-emitting diodes, particularly in the near-infrared range, where they outperform organic and quantum-dot counterparts. However, they still fall short of costly III-V semiconductor devices, which achieve external quantum efficiencies above 30% with high brightness. Among several factors, controlling grain growth and nanoscale morphology is crucial for further enhancing device performance. This study presents a grain engineering methodology that combines solvent engineering and heterostructure construction to improve light outcoupling efficiency and defect passivation. Solvent engineering enables precise control over grain size and distribution, increasing light outcoupling to ~40%. Constructing 2D/3D heterostructures with a conjugated cation reduces defect densities and accelerates radiative recombination. The resulting near-infrared perovskite light-emitting diodes achieve a peak external quantum efficiency of 31.4% and demonstrate a maximum brightness of 929 W sr−1m−2. These findings indicate that perovskite light-emitting diodes have potential as cost-effective, high-performance near-infrared light sources for practical applications. 
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  3. Abstract Rapid and scalable production of high‐performance composites remains a key challenge in achieving sustainable manufacturing. Here, Exo‐press frontal polymerization (EPFP), a novel and transformative method for manufacturing fiber‐reinforced thermoset polymer composites, overcoming energy efficiency, scalability, and curing complex geometries, is introduced. Unlike conventional curing methods that require prolonged processing times and high energy, EPFP utilizes exothermic heat to reduce curing time from hours to minutes with minimal external energy. Combining exothermic heat with press molding, the novel EPFP enables the efficient fabrication of complex geometries, such as airfoil skin sections, with high fiber volume fractions (above 60%). In addition, EPFP is compatible with commercial off‐the‐shelf epoxy by integrating frontal resin, showcasing its versatility and adaptability for diverse industrial applications. Composites manufactured using EPFP exhibit superior thermomechanical properties while significantly reducing energy consumption by 80% and production costs by 40%. This makes it a sustainable and efficient solution for polymer composites manufacturing. 
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  4. The all-solid-state battery is a promising alternative to conventional lithium-ion batteries that have reached the limit of their technological capabilities. The next-generation lithium-ion batteries are expected to be eco-friendly, long-lasting, and safe while demonstrating high energy density and providing ultrafast charging. These much-needed properties require significant efforts to uncover and utilize the chemical, morphological, and electrochemical properties of solid-state electrolytes and cathode nanocomposites. Here we report solid-state electrochemical cells based on lithium oxyhalide electrolyte that is produced by melt-casting. This method results in enhanced cathode/electrolyte interfaces that allow exceptionally high charging rates (>4000C) while maintaining the electrochemical stability of solid-state electrolyte in the presence of lithium metal anode and lithium iron phosphate-based cathode. The cells exhibit long cycle life (>1800 cycles at 100 °C) and offer a promising route to the next-generation all-solid-state battery technology. 
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  5. Abstract All‐inorganic lead halide perovskite nanocrystals (NCs) have great optoelectronic properties with promising applications in light‐emitting diodes (LEDs), lasers, photodetectors, solar cells, and photocatalysis. However, the intrinsic toxicity of Pb and instability of the NCs impede their broad applications. Shell‐coating is an effective method for enhanced environmental stability while reducing toxicity by choosing non‐toxic shell materials such as metal oxides, polymers, silica, etc. However, multiple perovskite NCs can be encapsulated within the shell material and a uniform epitaxial‐type shell growth of well‐isolated NCs is still challenging. In this work, lead‐free vacancy‐ordered double perovskite Cs2SnX6(X = Cl, Br, and I) shells are epitaxially grown on the surface of CsPbX3NCs by a hot‐injection method. The effectiveness of the non‐toxic double perovskite shell protection is demonstrated by the enhanced environmental and phase stability against UV illumination and water. In addition, the photoluminescence quantum yields (PL QYs) increase for the CsPbCl3and CsPbBr3NCs after shelling because of the type I band alignment of the core/shell materials, while enhanced charge transport properties obtained from CsPbI3/Cs2SnI6core/shell NCs are due to the efficient charge separation in the type II core/shell band alignment. 
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